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SF6 Molecule StructureSulphur hexafluoride gas (SF6) is employed as insulation in all parts of the installation, and in the circuit-breaker also for arc-quenching. SF6 is an electronegative gas, its dielectric strength at atmospheric pressure is approximately three times that of air.

It is incombustible, non-toxic, odourless, chemically inert with arc-quenching properties 3 to 4 times better than air at the same pressure.

Commercially available SF6 is not dangerous, and so is not subject to the Hazardous Substances Order or Technical Regulations on Hazardous Substances (TRGS).

New SF6 gas must comply with IEC 60376 (VDE 0373 Part 1). Gas returned from SF6 installations and apparatus is dealt with in IEC 60480 (VDE 0373 Part 2). SF6 released into the atmosphere is considered a greenhouse gas.

Fig. 11-1 - p-t diagram for pure SF6 gas
Fig. 11-1 p-t dia. for pure SF6 gas

With its contribution to the greenhouse effect below 0.1%, the proportion of SF6 is low compared to that of the better known greenhouse gases (carbon dioxide, methane, nitrous oxide etc.). To prevent any increase of SF6 in the atmosphere, its use should in future be confined to closed systems. Devices suitable for processing and storing SF6 gas are available for this purpose.

The gas pressure is monitored in the individually sealed gas compartments and in the circuit-breaker housing. The low gas losses (below 1 % per year) are taken into account with the first gas filling. Automatic make-up facilities are not necessary. The isolating gas pressure is generally 350 to 450 kPa at 20 °C. In some cases this can be up to 600 kPa. The quenching gas pressure is 600 to 700 kPa.

Outdoor apparatus exposed to arctic conditions contains a mixture of SF6 and N2, to prevent the gas from liquefying. The pressure-temperature relationship of pure SF6 gas is shown in Fig. 11-1.

Fig. 11-2 Conversion of water vapour content into dewpoint for SF6 gas at atmospheric pressure
Fig. 11-2 Conversion of water vapour content into dewpoint for SF6 gas at atmospheric pressure

Arcing causes the decomposition of very small amounts of SF6 gas. The decomposition products react with water, therefore the gas’s moisture content, particularly in the circuit-breaker, is controlled by drying (molecular) filters.

Careful evacuation before first gas filling greatly reduces the initial moisture content. Fig. 11-2 illustrates the conversion of water vapour content into dewpoint.

SOURCE: ABB

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Edvard Csanyi

Edvard - Electrical engineer, programmer and founder of EEP. Highly specialized for design of LV high power busbar trunking (<6300A) in power substations, buildings and industry fascilities. Designing of LV/MV switchgears.Professional in AutoCAD programming and web-design.Present on

6 Comments

  1. […] operating mechanism ensuring high operational reliabilityGas circuit breakers generally employ SF6 (sulfur hexaflouride) as an interrupting and sometimes as an insulating medium. In “single puffer”mechanisms, the […]

  2. […] GIL are filled with an insulating gas mixture of mainly nitrogen and a smaller percentage of SF6 gas.GIL was developed to meet a wide variety of requirements for installation and operation. A decisive […]

  3. […] Some systems are designed to add nitrogen automatically (figure 1) from pressurized tanks when the pressure drops below a set level. A positive pressure of approximately 0.5 to 5 pounds per square inch […]


  4. Daniel
    Sep 20, 2011

    @ Dean, yes SF6 is heavier then air, little over 5 times, however outside you must also consider atmosferical conditions will cause SF6 to mixt with the surrounding air. In closed rooms (eg. GIS buildings) the gas will drop to the bottom and if gastight, no aircirculation, it will stay there, in rest (eg. cable cellars) it is out most dangerous, in case of a leakage, it will push out ambient air making it impossible to breath. That is one of the reasons the pressure is monitored. FYI 1kg SF6 has a GWP of approx the equivalent of 22.300kg CO2


  5. dean richards
    Apr 12, 2011

    I’ve been wondering why, if SF-6 is quite a bit heavier than air, that it’s such an aggressive greenhouse gas. It shouldn’t be in the atmosphere as a blanket, but on the ground and sort of out of harms way. do you know why it’s considered a greenhouse problem if it should tend to stay on the ground?

  6. […] This post was mentioned on Twitter by Electric Engineering. Electric Engineering said: SF6 gas – as insulating and arc-quenching medium http://t.co/YuRRtEh […]

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